Hydrolysis of Phosphate Esters Mediated by New Unsymmetrical Binuclear Cu Complex
نویسندگان
چکیده
منابع مشابه
Structural, electrochemical, phosphate-hydrolysis, DNA binding and cleavage studies of new macrocyclic binuclear nickel(II) complexes.
New macrocyclic binuclear nickel(ii) complexes have been synthesized by using the bicompartmental mononuclear complex [NiL] [3,30-((1E,7E)-3,6-dioxa-2,7-diazaocta-1,7-diene-1,8-diyl)bis(3-formyl-5-methyl-2-diolato)nickel(II)] with various diamines like 1,2-bis(aminooxy)ethane (L(1)), 1,2-diamino ethane (L(2)), 1,3-diamino propane (L(3)), 1,4-diamino butane (L(4)), 1,2-diamino benzene (L(5)), an...
متن کاملNew mono and binuclear unsymmetrical Cu(II) bioactive complexes: Synthesis, Characterisation, Electrochemical and interaction studies with CT-DNA
A new series of mono and binuclear copper(II) complexes, [CuL1-3] and [Cu2L1-3]+, where, L = precursor complex prepared from condensation of salicylaldehyde, pyridine and various amines namely ethylene, propylene and butylene diamines with copper(II) perchlorate. All the complexes have been synthesized and characterized by FT IR, UV-Vis spectral and electrochemical methods. Cyclic voltammogramm...
متن کاملBinuclear Complex of Zinc and Copper with Unsymmetrical Macrocyclic Ligand as Sensitizer in Nanocrystaline TiO2 Solar Cells
Dye sensitized solar cells (DSSCs) are considered as one of the most promising alternativerenewable energy sources. In the structure of DSSCs, a photosensitizer composed of transitionmetal complexes is used to harvest light. In this work a binuclear complex containing twopropionitrile pendant arms [ZnLCu(OAC)]PF6 {L = 1, 6- bis (2-cyanoethyl) -2, 5-bis (2-hydroxy3-formyl-5-methylbenzyl)-2, 5- d...
متن کاملThe hydrolysis of phosphate esters of alpha-hydroxy acids catalyzed by molybdate.
Frequent observations have been made of the increased rate of hydrolysis of relatively labile phosphate compounds in acid molybdate solution (e.g. phosphocreatine (I), acetyl phosphate (2), and 1,3-diphosphoglyceric acid (3)). A study by Weil-Malherbc and Green (4) indicated that ATP, pyrophosphate, phosphoenolpyruvate, and fructosr B-phosphate were hydrolyzed appreciably in the pH range 3 to 5...
متن کاملThe Hydrolysis of Phosphate Esters of a-Hydroxy Acids Catalyzed by Molybdate*
Frequent observations have been made of the increased rate of hydrolysis of relatively labile phosphate compounds in acid molybdate solution (e.g. phosphocreatine (I), acetyl phosphate (2), and 1,3-diphosphoglyceric acid (3)). A study by Weil-Malherbc and Green (4) indicated that ATP, pyrophosphate, phosphoenolpyruvate, and fructosr B-phosphate were hydrolyzed appreciably in the pH range 3 to 5...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Bulletin of the Korean Chemical Society
سال: 2012
ISSN: 0253-2964
DOI: 10.5012/bkcs.2012.33.6.2037